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The relative order of stability of the conformers of 1,2-dimethylcyclohexane is

Question and options

The relative order of stability of the conformers of 1,2-dimethylcyclohexane is
  1. trans(aa) > cis > trans(ee)
  2. trans(aa) > trans(ee) > cis
  3. cis > trans (aa) > trans (ee)
  4. trans (ee) > cis > trans(aa)

Answer and explanation

Correct answer: D - trans (ee) > cis > trans(aa)
trans-1,2-dimethyl in the diequatorial form is most stable; cis has one axial methyl (a,e); trans-diaxial has two axial methyls and is least stable.

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