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The reaction of \(\mathrm{[PtCl_4]^{2-}}\) with two equivalents of \(\mathrm{NH_3}\) produces

Question and options

The reaction of [PtCl4]2−\mathrm{[PtCl_4]^{2-}} with two equivalents of NH3\mathrm{NH_3} produces
  1. cis-[Pt(NH3)2Cl2]\mathrm{[Pt(NH_3)_2Cl_2]}
  2. trans-[Pt(NH3)2Cl2]\mathrm{[Pt(NH_3)_2Cl_2]}
  3. both cis and trans-[Pt(NH3)2Cl2]\mathrm{[Pt(NH_3)_2Cl_2]}
  4. trans-[Pt(NH3)2Cl4]\mathrm{[Pt(NH_3)_2Cl_4]}

Answer and explanation

Correct answer: A - cis-\(\mathrm{[Pt(NH_3)_2Cl_2]}\)
Trans effect: Cl−\mathrm{Cl^-} has a greater trans effect than NH3\mathrm{NH_3}, so the second NH3\mathrm{NH_3} replaces a Cl trans to Cl, giving cis-[Pt(NH3)2Cl2]\mathrm{[Pt(NH_3)_2Cl_2]} (cisplatin).

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