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The number of distinct fundamental absorption bands observed in the infrared spectrum of a carbon dioxide molecule is

Question and options

The number of distinct fundamental absorption bands observed in the infrared spectrum of a carbon dioxide molecule is
  1. 1
  2. 3
  3. 2
  4. 4

Answer and explanation

Correct answer: C - 2
CO2\mathrm{CO_2} (linear, 4 modes) has a symmetric stretch (IR inactive, no dipole change), an asymmetric stretch (2349 cm−12349\ \mathrm{cm^{-1}}) and a doubly degenerate bend (667 cm−1667\ \mathrm{cm^{-1}}). Only the asymmetric stretch and the bending absorption are observed, so 2.

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