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Norrish Type 2 reaction of valerophenone involves

Question and options

Norrish Type 2 reaction of valerophenone involves
Figure
  1. γ\gamma-H abstraction followed by cleavage of α\alpha-bond
  2. γ\gamma-H abstraction followed by cleavage of β\beta-bond
  3. γ\gamma-H abstraction followed by dimerization
  4. α\alpha-bond cleavage followed by radical coupling

Answer and explanation

Correct answer: B - \(\gamma\)-H abstraction followed by cleavage of \(\beta\)-bond
Norrish type II: the excited carbonyl abstracts a γ\gamma-H to give a 1,4-biradical, which cleaves the bond between the α\alpha and β\beta carbons (labelled the β\beta-bond in the figure), giving the enol of acetophenone and an alkene.

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