Norrish Type 2 reaction of valerophenone involves
Question and options
Norrish Type 2 reaction of valerophenone involves

- -H abstraction followed by cleavage of -bond
- -H abstraction followed by cleavage of -bond
- -H abstraction followed by dimerization
- -bond cleavage followed by radical coupling
Answer and explanation
Correct answer: B - \(\gamma\)-H abstraction followed by cleavage of \(\beta\)-bond
Norrish type II: the excited carbonyl abstracts a -H to give a 1,4-biradical, which cleaves the bond between the and carbons (labelled the -bond in the figure), giving the enol of acetophenone and an alkene.
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