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In the following sequence of reactions (shown in the figure), the compound D is

Question and options

In the following sequence of reactions (shown in the figure), the compound D is
Figure
  1. propanal
  2. propionic acid
  3. propan-1-ol
  4. propan-2-ol

Answer and explanation

Correct answer: C - propan-1-ol
Ethanol + P/I2\mathrm{I_2} gives ethyl iodide (A); Mg/ether gives ethylmagnesium iodide (B); addition to formaldehyde gives CH3CH2CH2OMgI\mathrm{CH_3CH_2CH_2OMgI} (C); hydrolysis gives propan-1-ol (D). A Grignard reagent plus HCHO always gives a primary alcohol with one more carbon.

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