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Cyclobutane is obtained as the major product in

Question and options

Cyclobutane is obtained as the major product in
  1. photochemical activation of ethene
  2. thermal activation of ethene
  3. reaction of 1,2-dibromoethane with sodium metal in diethyl ether at high concentration
  4. reaction of 1,4-dibromobutane with sodium metal in diethyl ether at high concentration

Answer and explanation

Correct answer: A - photochemical activation of ethene
[2+2] cycloaddition of two ethene molecules is photochemically allowed (thermally forbidden), giving cyclobutane. Wurtz reaction of 1,4-dibromobutane at high concentration favours intermolecular coupling rather than ring closure; 1,2-dibromoethane gives ethene.

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